If it is in the original series:
Fourarms: too big, strong and durable
Diamondhead: same as above
Heatblast: too hot, powerful and durable
Wildmutt: better sense and stronger
Grey matter: smarter but would still lose
Xrl8: too fast and agile
Stinkfly: can fly and his stink can stick and hold spidey down.
uprade: can generate, can take over a tank and destroy spidey.
wildvine: too big, flexible and can attack with explosives.
Cannonbolt: too heavy and could squach spidey like a bug, but spideys speed could give it a chance.
Ripjays: On land spidey, in the water ripjaws
Benvictor: to big and strong
Ghostfreak: can become invisable and take over spideys body
Upchuck: can eat but would lose
ditto: spidey wins, he only needs to hurt one
Benwolf: same as wildmutt
Benmummy: same as wildvine
Eye guy: spidey cannot do any surprise attack and eye guy could melt or freeze him.
Way big: squaches spidey
In ben 10 Alien force:
Alien X: destroys spidey
Goop: he can re-generate, spidey vs goop would be an equal mathup
Brainstorm: spidey can win this
echo echo: unlike ditto here spidey needs to kill all clones, plus they can screem so echo echo wins.
humangosaur: same like way big, squaches spidey
swampfire: to powerful and can generate
chromstone: too durable, and strong
big chill: too cold and can freeze spidey
jetray: draw, jetray is quick and has lazor eyes.
spidermonkey: they have equal powers but spidey is bigger and stronget so spidey wins
Overall ben 10 wins
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