About every powerhouse can solo. And about every person that is the smartest can solo also.
Anyone from Iron Man up as far as I'm concerned. Once they start kicking nukes to the side without effort, we basically have nothing we can do. 24 hours is not enough time to get the UN to do anything, let alone get meaningful work done preparing.
The only one that may be inconvenienced would be Hulk, since he'd probably instantly get cancer...
As far as "weakest"? Depends on how you define weak. Xavier is probably the simplest answer to this, considering he can TP us all into the dirt, or make us nuke ourselves, etc.
Alternatively, I'd go with E2 Grundy, considering we can't kill him.
Well, the OP explicitly stated that the "weakest possible" people only, so those few suggestions are a bit over the top.
Personally, in scenario one, without any knowledge whatsoever of the enemy's weaknesses at all, I'd say venom. The same way he took over New York in Web of Shadows. He could infect everyone one by one, creating a monstrously powerful army. With a Symbiote army the Size of New York, I think Venom could take over the world from there. Remember, we don't know his weaknesses in scenario one, so we wouldn't know to use sonic weaponry until his army is already too big, so he'd have an advantage already.
As for Scenario two, it's a stretch, but I argue someone like the Riddler could do it. He's extremely clever, and would probably stir up some bad blood between nations before he put his main plan into actions. That way the countries would be far too interested in war to deal with him on the sidelines, allowing for him to pick them off one by one.
Just my opinions though.
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