The Asgardian goddess Brunnhilde is one of Asgard's mightiest warriors and the leader of the Valkyrior, Odin's choosers of the slain. Known simply as "Valkyrie" outside of Asgard, she is a long-time member of the Defenders and more recently also a member of the Avengers.
Valkyrie would be my pick, I believe she is stronger than Sif. Maybe her sword Dragonfang may also give her an edge, even if Sif trains all the warriors of Asgard. I'm not really sure though!
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