Brainiac appears in 28 issues in this volume.
Superman's Return to Krypton!
The Secret Identity of Superman! / The Interplanetary Circus! / The Night of March 31st!
When the World Forgot Superman!
January 1, 1962
Lois Lane, the Super-Maid of Krypton!
The Amazing Story of Superman-Red and Superman-Blue!
The Team of Luthor and Brainiac!
The Tyrant Superman!
The Untouchable Clark Kent! / Tales of Green Kryptonite No. 1 / The Triumph of Luthor and Brainiac!
Super-Brother against Super-Brother!
30th Anniversary Issue 1938-1968: Classic Tales Featuring Superman's Friends and Foes!
Lois Lane... Dead... Yet Alive / Superman's First Exploit
Featuring Famous First Golden Tales!
Superman battles the War-horn! / The Greatest Green Lantern of All!
The Man Who Murdered Metropolis!; The Warriors of Lightning Valley!
The Double-or-Nothing Life of Superman!
Too many Crooks!
Let my People Grow!
Better Vengeance Through Chemo-stry! / Super-Visions from Beyond
Kandar lives Again! ...If You can call this Living! / Mind over Money!
The Living Legends Of Superman
October 1, 1984
Whatever Happened to the Man of Tomorrow?
The Beast From Krypton
October 1, 2007
The Third Kryptonian, Part Two: The Escape
December 1, 2007
New Krypton, Part Six: Invasive Surgery
January 1, 2009
December 1, 2009
Last Stand of New Krypton, Part 3: Destiny
May 1, 2010
Irony in Ire
June 1, 2010
The Comeback; Geometry; Grounded, Prologue: The Slap Heard 'Round The World
August 1, 2010
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