Cap appears in 17 issues in this volume.
The Bald Boy of Steel / Krypto's Super-Movie Stunts! / The Sacrifice of Kid Psycho!
The Seven Insect Lives of Lana Lang!
March 1, 1966
The Twilight World of No Return!
April 1, 1966
Superboy and His Super-Friends!
Krypto's Cat-Crook Caper! / The Youth Who was Braver than Superboy!
The Scoundrel of Steel! ; Krypto's First Romance!
December 1, 1966
The Menace of the Mechano-Master! ; When Lana Lang First Suspected Clark Kent!
January 1, 1967
Mystery of the Mighty Mite ; Superboy's Blind Identity!
April 1, 1967
Superboy and Krypto's Most Terrific Battles!
June 1, 1967
The Town That Hated Superboy! ; The Samson of Smallville
June 1, 1967
The Wizard of Odds!
July 1, 1967
No Mercy for a Hero!
September 1, 1967
Superboy Goes Ape! ; The Shyest Boy in Town!
October 1, 1967
The Big Fall ; Superboy's Civil War Time Trip!
December 1, 1967
Superboy's Stolen Identity!
January 1, 1968
Superboy's Greatest Gamble! ; The Canine that Outclassed Krypto!
June 1, 1968
Challenge of the Cosmic Invaders ; Superboy's Secret Hideaways
January 1, 1969
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