a quick google search finds this post. http://www.comicvine.com/forums/spider-man-167/spiderman-prep-feats-1495548/
Ends of the earth suit
Amazing spider man 2 against anti vulture device
Amazing spider man 3 dr octopus metal bonding chemicals.
Anti electro suit
Hacking the spider armor
Pretty much anything to do with Horizon Labs.
Acid webbing against Sandman
Cryocapsules against Hydroman
Thermo-something gel against Equinox
Bulletproof suit against Massacre
Magnetic webbing against Massacre
Invisible/sound-proof suit against Kingpin and Hobgoblin
also more recently he helped create the device that could remove Electro's powers
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