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Little is know of Rex Hunters past but what is known is that he was once one of Rip Hunter's students. He had great potential but Rip kicked him out of the Time Masters when he was caught trying to throw a 10 year old Luthor in front of a train and change the past. His real name is Jason Goldstien but like all great Time Masters he changed it so no villian could ever truely find him.
Major Story Arcs
52 Pick Up
Rex still mad at Rip went to work secertly, for the Time Stealers. He would go with the evil Supernova and try to change the past to make themselves the heros. But Booster and Rip stopped them and Rex was taken back to Rip's lab were he was tortured .Before Rex could tell Rip any thing he was ripped out of the time stream.
The Time Stealers had found out Rex's real name and gone back in time and killed him in crib, and made it as if he had never existed.
It turns out that instead of not existing Rex's body was turned into pure chornal energy. He could travel threw time but he could really effect anything and it was diffucult to hold a psyical form. So he kidnapped Goldstar, Booster Golds sister and takes her to Vanishing point, where its revealed that Rex has found a portal that would make him Time's Ultimate Master. Booster and Goldstar are able to stop him and Skeet is able to make him into a solid form long enough for Booster to stab him.
Being stabbed does not truely kill Rex but his bodies energy is dispersed threw the time stream to never be seen again.