I'll give it to the Spiders although I am a lil biased lol but
If Spider-Man takes out the first two X-Men Cyclops and Wolverine he would probably have the best chance. Although Cyclops has tagged Spider-Man before situations such as these Spider-Man is playing. If he focuses and actually has his head in the game more than likely Cyke will be easy for him to beat. Wolverine is the same way usually. Although Wolverine has his healing factor and superior fighting skill. Spider-man is just too fast and strong and has a few years of experience himself plus his own martial arts training. He has several times humiliated Wolverine in fights usually used comically but still when angry and not holding back too much.
Next Venom should fight Gambit and X-23 because although Gambit does indeed have his Death powers I have a feeling based of the PIS that is usually involved with Venom he would probably be resistant to his ability to control him also since if I remember correctly it's currently been stated that Gambit can only charge inorganic matter the suit would be a good source of protection for Flash although Gambit's ability to affect organic over inorganic is often debated I think in a recent issue of AVX Vs it was stated he only charges inorganic. Next Venom vs X-23 would just be a great fight comparing both their lethal natures I think Venom would have an edge on her for the same reasons that Spider-Man has over Wolverine plus the suits extra abilities such as shapeshifting attacks and feral nature.
Next I think Kaine should be more than a match for Beast and Deadpool. Since Kaine possess much of Peter's knowledge he is more than likely the next best choice against Beast intelligence however Beast is of course smarter I'd still hope that Kaine would atleast be able to neutralize some of his equipment if need be. Next as stated by Sabretooth recently Beast hold's back too much during fights despite being stronger and smarter than Wolverine. Kaine has only just recently begun to comprehend holding back and will no doubt push Beast past his limits in a fight. Also Kaine like Peter is a quick thinker and makes plans on his feet. Next Deadpool will be nothing to Kaine because part of what helps Deadpool vs Peter is Peter's holding back Nature if Kaine is aware of his healing factor he will hold back none and simply slice him apart steal his weapons and use them on him or summon spiders to chew him out from the inside out.
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