@winter_kills: Your ideas seem more like the direction AoS is taking. It does sort of feel like Secret Warriors' early days. As for the spin-off, I stand by my W.C.A. (World Counterterrorism Agency) idea. I'm sure that a Bobbi/Hunter centric show will have to include a larger cast...
Then again, Hunter in the comics is on S.T.R.I.K.E.
Loosely base it off of Jim McCann's Hawkeye/Mockingbird run(s). That way you can introduce characters like Twitchy, London and even Dominic Fortune. Then, once in a while, have Maria Hill, Black Widow and Hawkwye cameo.
That's what I'm thinking.. I get that sometimes the cast's ethnicities will not be true to the source material, but in this particular character's case the ethnic background affects her characteristics. If she's not English then she can't be related to Captain Britain. If she's not Japanese then she can't have the passedon skills she acquired in her body-snatching phase.