This goes to Baymax.
Po is lacking in actual skill by comparison. His plot driven techniques (wuxi finger hold) rely on and affect the chi of the opponent. Baymax, as a machine, has no chi.
Baymax has greater mobility than Po. He can fly and has fast reaction time.
Durability? Well, Baymax has a carbon fiber exoskeleton. Po can't destroy that by any feat seen. Given his height and the low weight of carbon fiber, it is more likely that Po would knock Baymax back at best unless he's pressed against a surface that he can't break through when hit.
Baymax could simply grab Po and fly him into a river or ocean or high into the sky until he loses consciousness. These all remove any need to even consider Po's durability.
Baymax wouldn't even have to hold back against Po because Po isn't human. Considering Baymax could sheer through modern steel beams without issue, I think it's easy to put him above Po in feats.
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