Daken wins: there is no such thing as pheremone immunity, except for skrulls and kree. Daken has used his pheremones on Ares, Wolverine, Skaar, Deadpool and Venom.
Mister X is in fact a telepath:
http://marvel.wikia.com/Mister_X_(Earth-616)
Yes, he does map neural pathways or whatever, the way he does this is via telepathy, also he stated himself when he fought and killed Vorr, that Asgardians have similar minds to humans as he could read Vorr. He was also shown reading Amadeus Cho, but because Cho is a hypermind, X could not make sense of Cho's high paced calculations.
It makes no sense for his power to not be telepathic, otherwise Wolverine going into a berserker rage would have no effect on X.
But that doesn't matter as Daken is immune to telepathy, his kind contains a trap that affected both Miss Sinister and Xavier.
Add to that, his enhanced senses and healing factor and X has no chance. Even without Muramasa, Daken's bone claws can cut steel.
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