Spidey, Wolverine, and Hulk. Marvel really has a main 4 though w/ Iron Man a strong candidate not only as the 4th but just beaten out of the 3rd spot by Hulk.
The debate is really between Spider-Man, Iron Man, Hulk, Captain America, and Wolverine ....And I choose Spider-Man of these five cuz he's Stan Lee's guy (as he nicknames himself Peter Parker) and he's maybe the best stand-alone hero in the Marvel Universe. If you stand alone and have as many issues as Spidey does, drawing many intimate and memorable moments, he deserves this title the most.
Since science and evolution do run supreme in my book, I've got what popular vote seems to also have w/ Thanos being the smartest, then Reed and then Doom.
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