Not sure if this forum has anything against necro-posting. If so, pardon me and feel free to remove.
I was thinking it could go something along the lines of:
1- Superior Spider-man
2- Black Cat (Both for her history with Spidey along with the fact that Ock may or may not have beaten her almost to the brink of death?
3- Silver Sable (Madame Web said she was alive, good way to tackle Ock's past endeavors)
4- Alpha (resident powerhouse and SSM being a magnificent bastard he'll soon be Ock's personal powerhouse)
5- Toxin (he's an interesting character to explore, especially his reactions to SSM's recent actions, how does the lethal protector feel about the new Spider-Man?)
6- Lizard (waiting for the No Escape arc to conclude but it would present an interesting dynamic)
I consider this a good mix between brains, brawn and classic spidey fun.