Donquixote Doflamingo appears in 21 issues in this volume.
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Issue #25
The 100 Million Berry Man
January 5, 2010
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Issue #32
Love Song
February 2, 2010
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Issue #52
Roger and Rayleigh
June 2010
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Issue #54
Unstoppable
July 2010
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Issue #56
Thank You
February 2011
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Issue #57
Paramount War
June 2011
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Issue #58
The Name of This Era Is "Whitebeard"
September 2011
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Issue #59
The Death of Portgaz D. Ace
December 2011
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Issue #61
Romance Dawn For the New World
March 2012
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Issue #67
Cool Fight
June 2013
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Issue #69
S.A.D.
December 2013
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Issue #70
Enter Doflamingo
March 2014
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Issue #71
Coliseum of Scoundrels
June 2014
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Issue #72
Dressrosa's Forgotten
September 2014
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Issue #73
Operation Dressrosa S.O.P.
January 2015
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Issue #74
Ever At Your Side
April 2015
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Issue #75
Repaying the Debt
August 2015
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Issue #76
Just Keep Going
November 2015
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Issue #77
Smile
February 2016
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Issue #79
LUCY!!
August 2016
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Issue #80
Opening Speech
November 2016
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