Pain appears in 31 issues in this volume.
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Issue #27
Departure.
December 2007
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Issue #29
Kakashi vs. Itachi!!
May 2008
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Issue #36
Cell Number 10
February 2009
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Issue #37
Shikamaru's Battle
February 2009
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Issue #39
On the Move
March 2009
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Issue #40
The Ultimate Art
March 2009
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Issue #41
Jiraiya's Decision
March 2009
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Issue #42
The Secret of the Mangekyo
April 2009
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Issue #44
Senjutsu Heir
April 2009
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Issue #45
Battlefield, Konoha
July 2009
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Issue #46
Naruto Returns
October 2009
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Issue #47
The Seal Destroyed
February 2010
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Issue #48
The Cheering Village
June 1, 2010
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Issue #49
The Gokage Summit Commences
October 2010
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Issue #50
Water Prison Death Match
February 1, 2011
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Issue #52
Cell Seven Reunion
September 2011
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Issue #54
Peace Viaduct
January 2012
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Issue #55
The Great War Begins!
March 2012
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Issue #56
Team Asuma, Reunited
May 2012
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Issue #57
Battle
July 2012
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Issue #58
Naruto vs. Itachi
September 2012
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Issue #59
The Five Kage
November 2012
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Issue #60
Kurama
February 2013
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Issue #61
Uchiha Brothers United Front
May 2013
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Issue #63
World of Dreams
November 2013
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Issue #64
Ten Tails
January 2014
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Issue #67
An Opening
October 2014
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Issue #68
Path
December 2014
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Issue #70
Naruto and the Sage of Six Paths
June 30, 2015
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Issue #71
I Love You Guys
August 2015
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Issue #72
Uzumaki Naruto
October 2015
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