I only know of 
 
1. Golden Mace 
 
2. Nemean Lion Sin 
 
3. Arrow of Heraclues 
 
4. Helm of Hades 
 
5. Sword of Perseus 
 
6. Shield of Peleus 
 
Any other ancient mythical gear/weapons that Hercules has used? Or are those the only ones that he has used so far?

Hercules borrowed the Sun Chariot of Apollo and used it for transportation in both Bob Layton Mini-series set in the future.

Hercules borrowed the Sun Chariot of Apollo and used it for transportation in both Bob Layton Mini-series set in the future.

@Wolfrazer:

Not that I can think of right now.

@Wolfrazer said:

I only know of 1. Golden Mace 2. Nemean Lion Sin 3. Arrow of Heraclues 4. Helm of Hades 5. Sword of Perseus 6. Shield of Peleus Any other ancient mythical gear/weapons that Hercules has used? Or are those the only ones that he has used so far?

As for the "what they do" part of your post:

1. Supposed to be indestructible for nearly anything known. I don't know how it compares to other indestructible items like adamntium or enchanted uru. I imagine it is up there.

2. Virtually impenetrable skin. Since the lion's own claws were able to skin it I wouldn't be surprised if there are other things that can cut it, but those should be very rare.

3. Dipped in Hydra's blood making them extremely poisonous and painful to even immortals.

4. Turns him invisible even to other immortals.

5. Really sharp sword that can cut through nearly anything.

6. Can temporarily turn things to stone. Wasn't it supposed to be a reverse engineered model of the one Perseus used and one of Athena's Aegsis?

7. Sun Chariot of Apollo It can travel faster than light across space or between dimensions. It can create an atmosphere and gravity letting its occupants survive without the aid of machinery.