This is first off one of those fights that's so greatly balanced it could be really great or really bad. Though seeing how both characters are almost always written and sold well it'd probably be great.
Most of their stats are quite even with the various super soldier traits rivaled by the arcani's arts. They both are fast crafty and so on.
However Ivana has better gear, Slade usually has pretty average armor which is far less dependable then Vibranium. Ivana has the armor to take a few hits where Slade does not though he can likely keep fighting through the pain for awhile Resiliance alone isn't to likely to help.
Ivana also benefits from additional powers, Slade has fought a lot of foes so odds are these powers and mystic martial arts things won't throw him off his game. They do however keep an edge on Ivana's odds.
Lastly I'd argue Ivana has better experience. Slade has had a lot of fights and has a lot of experience he also however more or less fights the same foes. Comics have a more reacuring cast of opponents for there characters. The RPG section though is much more diverse who Ivana fights in Shadow Wars isn't the same as who she fought in VZ, who she fought in VZ she didn't fight in Japan, who she fought in Japan isn't who she fought when she took over VZ and so on. In other words where Slade's next fight is Slade vs TT round 19 Ivana's next fight is probably something new. Meaning she's probably got a better sense of diversity and preparation.
However assuming they make it to round two the odds will be much more in Slade's favor and he'll be more likely to win. What little prep we have seen for Ivana has always been more for a distinct enemy(such as vampires/lycans) and for large scale battles. Not necessarily custom load outs for one particular foe or anything along those lines
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