Willpower is at the very center of the spectrum, with no control over the user. Theres a lot of reasons why the Guardians chose green over red, orange, violet, or the myth of white
Red: Atrocitus harnessed red independently of the Guardians. Even so, its destructive, brain-damaging, and corruptive. Thats the opposite of peace.
Orange: Larfleez has orange all to himself. The Oans had an agreement with him. The obsession with possession wouldn't have helped either.
Yellow: GLs are chosen for their ability to overcome great fear. Harnessing yellow defeats the purpose. Plus: the classic Yellow Impurity and, post-retcon, Parallax.
Blue: Blue was not harnessed until very recently in-universe, and by a former Guardian. To my knowledge, blue wasn't even known of when the Oans formed the GLC. But I do think that the GLC would really benefit from having Blue Lanterns on rank. Their relationship is perfect symbiosis.
Indigo: Like blue, indigo was first harnessed not too long ago. It didn't exactly have an origin pre-Flashpoint, so according to the New-52: all the members are brainwashed former criminals found by Abin Sur, keyword brainwashed.
Violet: The Oans think the women of Zamaron are weakened by their obsession with emotions and love. Its also at the end of the spectrum, so it warps the user's ideologies.They wouldn't have chosen violet even if the Zamaroans didn't harness it.
White: Also not available until the recent stories and never completely controllable.
Black: No response needed.
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