When did Superman first use Heat Vision and Ice Breath??

After catching up to date with the New 52 storyline of Superman, I've began to read the original series of Superman comics by Jerry Siegel and Joe Shuster. I've realized that this portrayal of Superman is very different to the modern take on Superman, he lacked some of the powers that are prominent today, like flying (he leaps instead), Heat Vision and Ice Breath; I want to know when those powers were first introduced.