Superman or the X-Men.
Superman's got: Brainiac, Zod, Bizarro, Luthor, Doomsday, and Darkseid started out as his. All very very iconic, and those are just a few.
The X-Men ones while not as iconic I just think are fun and diverse. Some of my favorites are En Saba Nur, Magneto, Juggs, the Brotherhood, Dark Phoenix, occasionally the Shi'ar, Omega Red, the sentinels, and the brood.
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