... Haki is a sense, like sight, smell, or touch. Chakra is not. Chakra is a balance physical energy mixed with spiritual energy, and sometimes some nature energy thrown it. Its the difference between light and sight, energy vs senses.
Now than, while he might have a life force, he isn't capable of mixing it with physical energy, and thus doesn't have Chakra. However, even if he did, Genjutsu also relies on the Chakra coils that run through the brain, which is an anatomical feature that is only found in the Naruto universe. Being completely fair, Sasuke wouldn't be able to use Genjutsu, and Zoro would have full access to Haki's capabilities.
However, considering this is a neutral universe, where all characters can use their powers, none of that matters. Genjutsu can be used. So, this is a classic power vs versatility battle. Despite what people think though, Amaterasu and Susanoo don't guarantee any sort of success. They might be useful tools, but Susanoo has been broken, and Amaterasu has been endured, and Zoro has a knack for breaking and enduring. Zoro has shown strength beyond more or less any Naruto character, and can almost certainly power through him like the Raikage did. Genjutsu is going to be rendered useless. Genjutsu is easily overcome by senses not usually used, such as Byakugan or the senses of insects, and Haki would undoubtedly fall into this category. Also, large sensory overloads such as chile smell or pain has been known to break people free from genjutsu, and going by the fact that Sasuke is one bloodlusted mofo which Zoro can see through his senses, he would most likely break free of it immediately.
Zoro wins this 8/10
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