Jackie doesn't necessarily have to make him explode. He has an awesome understanding of the human anatomy (he has rebuilt his own heart and someone's eardrums and created a lifeform capable of giving birth), he could create an embolism in his bloodstream and cause him to have a stroke or heart attack for example, or replicate water in his lungs (he has created water from the darkness) and so on. Now, assuming you meant no darkness manipulation whatsoever inside his body, then you might have a fight, though I know little of XO.
One thing I can think of right off the bat though, is that Jackie could manipulate the darkness under his armor and the spaces in-between for a variety of possible effects (like strangling him using the darkness under his armor).
For the plasma to be effective, it would need to incinerate Jackie completely (nothing left), because if there is anything left, the darkness can just regenerate Jackie. If he can incinerate Jackie completely, the way I see it, depends on who is first on the draw, and how fast that plasma works. Jackie is exceedingly durable. He has tanked explosions (rpgs, one that blew up his mansion, so on) before without a scratch, and is hard to put down.
Also remember that Jackie's strength is in the tons (for which we do not know the upper limits), so I am guessing he might be able to hurt XO if it came down to hand to hand...but I don't know XO's strength, speed, and durability with the armor.
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