Depends on if Wonder Woman has her weapons or not (including her lasso, bracelet and tiara).
If she has her weapons? Wonder Woman has a definite chance of winning.
If she has no weapons, or just has her bracelets? Wonder Woman has a definite chance of being dead. She might survive, but I don't see her winning without being obscenely lucky, even with her vastly superior fighting skill and experience, if she doesn't have at least the lasso.
It also depends on if Supergirl is bloodlusted or not.
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