@mortein: one piece doesn't have dragonball style power scaling so that doesn't work.
Still, when it comes to strength speed and durability, Z was on pair with current Luffy, while Shiki was on pair with pre time skip Luffy, thus difference in speed and strength and durability between Z and Shiki should be more or less equal to difference between pre time skip Luffy and current Luffy, and that's a pretty large difference, so large in fact that Z should be able to take him out with few punches.
Luckily, Shiki has pretty cool DF, which might help him prolong his inevitable defeat, so he doesn't get beaten up in few seconds.
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