Captain America
Midnighter can beat him easily. Mirror Master can beat him instantly. Nightcrawler should be able to 'port his head off, or at the very least 'port his shield away for Longshot to shoot him. Sylar has lots of ways to beat him with ease.
Hawkeye
Same as above.
Hulk
Midnighter and Longshot are of little use here. Mirror Master can blind him, and might be able to win by transmuting or turning him inside out. Nightcrawler might be able to 'port his head off. Sylar has a chance with his abilities to transmute and disintegrate. He could possibly use his empathy power to calm Hulk down into Banner.
Iron Man
Midnighter and Longshot have little chance. Mirror Master can probably transmute him, and he can have lots of fun with Tony's shiny armor. Nightcrawler has a chance at tele-dismemberment, but Tony's speed would make it very difficult. Sylar's empathy, TK, transmutation, electricity manipulation, and disintegration should be of use here.
Vision
Same as above, but tele-dismemberment won't work because of intangibility.
Thor
Midnighter has a solid chance, since he has much better speed and has gotten through the durability of Jack Hawksmoor, Maul, Apollo, and a female version of Apollo. Longshot probably can't get through his durability. Mirror Master can play around with his shiny helmet and hammer, and should be able to transmute him. Nightcrawler could probably 'port his head off. Sylar would go after him the same way he'd go after Tony.
(*) I'm assuming current Nightcrawler is still the AoA version.
Interesting question: Could Kurt teleport Mjolnir away?
In conclusion: I think the unlikely team will likely take the majority, largely thanks to Mirror Master and Midnighter.
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