In character, Cyclops and Iron Man both are excellent tacticians and leaders, and all have experience with teams. The villains do have the advantage of having similar skill sets, but will have difficulty coordinating attacks.
Cyclops vs Captain Cold. Both have narrow and wide area attacks. I see Cyclops as having the superior power here. Summers would win a beam vs beam clash, has superior tactics, and can ricochet his optic beam if needed.
Killer Frost vs Human Torch. Johnny can't go all out due to teammates, and with Frost's heat absorption, I don't see him lasting too long.
Iron Man vs Mr Freeze. I like Mr Freeze and think he's smart enough to put up a good fight, but will ultimately lose against Tony.
Icicle vs Spider-Man. Icicle seems to be able to make ice constructs only. As long as Spidey stays active, he can win. If Icicle can tag him he may be able to bury Parker in ice. 50/50.
I think Cyclops would finish Icicle if Spidey loses and the combined efforts of Tony and Scott would beat Killer Frost. I do see her as the biggest threat though.
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