Which EMH version of Ultron kinda matters. If we're going by the OP image, it would be Ultron-6. In which case he would definitely be a tough customer to take due to his 'pure adamantium armor'. He took the full brunt of Thor's lightning, Ms. Marvel's beams, and Iron Man's uni-beam without even flinching. Bear in mind that all these heroes were pissed at this point (on account of Ultron having captured them and replaced them with robot clones), and since he's a robot, none of them were holding back.
He was only beaten when Vision used his phasing to detach Ultron's head from his body (Man...if there ever was a better time for MMH to be in the New 52 League, huh?).
But even with that said, Ultron-6 is still lacking in feats. I think a morals-off and bloodlusted JL stands a decent chance of victory. It all depends on how long they stop squabbling and start working together, and how long it takes them to figure out that Ultron's armor is impenetrable. One option is that Cyborg could possibly use his tech to override Ultron's systems. Another is Flash vibrating through Ultron (though I don't remember if he actually showed this capability in the movie).
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