This is close, but I would give a slight edge to Azula and Zuko.
Wan and Azula are, I believe, the powerhouses here. They are both firebending prodigies. But while Wan may have an advantage in raw talent and training, Azula has an advantage in deadly ferocity and experience in fighting other firebenders (she's probably been in agni kais since she was a kid).
And if you compare Zuko and Korra, Zuko is just... better. Korra has done some to impress me as a firebender, but Zuko has done more. In addition, he has some very impressive non-firebending martial arts feats as the Blue Spirit.
So here's how I see it playing out:
Possibility 1: Azula fights Wan, while Zuko fights Korra. The Azula/Wan fight could seriously go either way, but I think I would give it to Azula maybe 6 times out of 10, because of the advantages I've stated above. And Zuko would beat Korra probably 7-8 times out of 10. He just has better form, better control, better martial arts skill, etc.
Possibility 2: Azula fights Korra, while Zuko fights Wan. Azula would wreck Korra. There's no two ways around that. And while Wan would also beat Zuko, I think Zuko would still be able to hold out for a little while. I think there's a decent chance he would survive against Wan long enough for Azula to finish her fight and come help him out.
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