I think the X-men can take this, but they have to have exceptional teamwork and mutual defense to pull it off.
Leadership: Wolverine is probably best suited to handle sudden intergalactic war, having multiple wars of experience, but Storm might be useful if Wolverine goes a bit too frothy in the process of shredding Chitauri that threaten civilians. If communication gets spotty, Quicksilver functions as a messenger and boots on the ground bonus.
Civilian Evac: Quicksilver can be working to clear paths for civilians to get to better-protected ground floors, while Blink can evacuate the hardest to reach and longest to escape places. Quicksilver being insanely fast in DoFP, I suspect he'll also be contributing against the Chitauri ground forces and those occupying buildings with stairs. scouting for enemies, twisting the occasional authority figure's hat backwards, etc...
Strategic and Tactical Transportation: Blink is the MVP here. Quicksilver can scout out enemy activity, and Blink can get Ground and Anti-Air forces where they will do the most good.
Mobile General Fire Support: Storm and Iceman. Storm's lightning and tornadoes could be devastating and strongly discourage (or even spook - "what the... THOR IS HERE!?!") Loki and his fellow aerial Chitauri raiders. I'm confident Storm could also eventually take down a Leviathan with her Lightning in similar ways to Thor, though I'm not sure she has quite his potency. She's a bit more consistent and broad-ranged, though, which is useful against the large number of attack craft the enemy showed in Avengers. Iceman is quick and can traverse height and distance with speed and ease, and his attacks are a reasonably wide area of effect. Storm and Iceman, working in concert, are going to have to stand in for Ironman (and a part of Thor's role), and those are big (ostentatiously gold and red) boots to fill.
Ground Forces: Wolverine, Warpath, and Beast are going to be tearing apart anything that gets close to them, and are either fast enough to evade fire or capable of regenerating through an accurate shot. Warpath and Beast might die with enough numbers or to exhaustion, but Wolverine will at least occupy a fraction of them trying to keep him dead.
Anti-Air Forces: Sunspot and Bishop are going to be the heavy hitters here, and I think Bishop absorbing Sunspot's energy will probably be the team's best defense against Leviathans (though Iceman might be close). Attackcraft grouped together will also regret such foolish tactics. This team more than replaces Hawkeye's role, and with Blink ferreting this potent duo where ranged firepower is needed most, they can remain useful long after Hawkeye ran out of arrows.
Dealing with Loki: Storm and Iceman seem the most likely duo to get Loki isolated (by freezing or t-bolting all of his nearby allies, with windstorms keeping the rest at bay), off his game (gathered lightning bolts simply has to have him checking around every corner for his "brother" and that damnable hammer...), and out of his attackcraft (bringing down the craft itself through lightning/ice, or goading him into Sunspot and bishop's full powered firing lane.
Once Loki is on the ground, Quicksilver relieves him of his staff and, assuming Quicksilver can hit hard enough, Loki's dignity in the blink of an eye, and a second or three later has it at Stark tower (assuming they have reason to know what they need and why at that point... a bit of a big if, but possible with Beast on the payroll and involved as much as the Avengers were).
This relies, however, on a great deal of teamwork, which I feel the X-Men of DoFP have displayed reasonably aptly (they died honorably, pulling off combination attacks against foes tiers above them and surviving a surprising amount of time).
I give the X-Men a 7.5 out of 10. Quicksilver's mobility is huge, and Storm has displayed some seriously wide-ranging and highly destructive feats that could help the otherwise flightless X-Men deal with the aerial mobility of the Chitauri forces. The X-Men have displayed impressive levels of destructive force (enough to convince me that Leviathans can be taken down) and enough unspoken teamwork to garner the win. Blink grants the team a level of mobility that the Avengers can only dream of, which allows their comparatively small levels of firepower (Iron Man alone is immense, and Thor's crowd control and heavy hitting/durability will be sorely missed, not to mention an unleashed hulk) to shine in all the right ways.
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