Well, I'm kind of on the fence with this one. Daredevil can do things Cap can't and vice versa. Without any PIS or CIS, it would be a long drawn out fight.
Skill: Eh, about even. I would say that while Captain America might have more experience, DD knows his stuff and is basically a grandmaster of Ninjutsu. Coupling that with his knowledge of boxing and other martial arts, I'd say that there isn't a sole victor in this category.
I'd say Captain America would take this 6/10, but DD ain't going down without a fight.