As Buufy has been taxed to her strength limit in various episodes by some vamps (like Angel), she may be only a little stronger than one. Now I don't know what the strength of a vamp is in the Buffyverse - but from the looks of things, it would seem to be at least about 4 - 5 times as strong as a human - so this puts Buffy's strength at around the 1000 - 1200 lb mark. We know her endurance and agility/reaction time are up there with vamps as well.
This would make their abilities similar to Marvel universe vamps and Cap has defeated Baron Blood before (with his shield I admit).
Cap is peak human in his physical abilities and perhaps a little enhanced (due to the SSS in his veins) on endurance as it helped eliminate fatigue poisons. This was the basis of his character - he is the best human possible - he does not rely on super powers to get the job done and as such was the inspiration he was to those around him.
So Buffy may be slightly quicker and stronger. For endurance I seem them both as equal. I also think that Buffy is likely more durable.
However Cap knows far more about Hand to Hand fighting than Buffy.
Overall, I don't see the slight physical advantages that Buffy has getting the win over Cap's fighting skills and experience.
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