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His first appearance in any media was in Batman TAS as a throwback to the old Batman villains from the TV show with Adam West, he even used bad puns. It is revealed he was a comedian brainwashed by the Joker. He presumably returned to a normal life. He was voiced by Stuart Pankin.
"The big bad Bat-guy. I knew you'd ketchup to me sooner or later. How I relished this meeting. You, the dynamic dark knight versus me, the conceptual Condiment King! Come Batman. Let's see if you can cut the mustard."
His first chronological appearance was in Batgirl: Year One battling Batgirl ( Barbara Gordon) and Robin ( Dick Grayson) and lost.Years later he was jokerized during the time Joker thought he was dying ( Joker's Last Laugh). He was confonted in a mall by Ted Kord, Black Canary and Tim Drake who all vastly underestimated him,believing him to be a loser. However he revealed that during his stay in Arkham, Poison Ivy taught him more about spices which he put to use in his newest "recipes." He used his condiments on the three heroes sending them into anaphylactic shock,until Beetle use the milk to stop the burning, and remove the bomb from the mall as Condiment King is recaptured.
Recently he was easily defeated by Tim and Batman. He has joined forces with General Immortus and other new second-rate villains. Condiment King was responsible for the Human Flame's introduction to General Immortus and Professor Milo. His head was squashed by an outraged Human Flame.
Condiment King has weapons that shoot out various condiments, he's been known to use his knowledge to cause anaphylactic shock. It was stated the villains Immortus works with have received upgrades. Whether Condiment King received upgrades or not has yet to be seen.
In Other Media
Condiment King appeared in Batman: The Animated Series