During World War II, Steve Rogers volunteered to receive the experimental Super-Soldier Serum. Enhanced to the pinnacle of human physical potential and armed with an unbreakable shield, he became Captain America. After a failed mission left him encased in ice for decades, he was found and revived by the Avengers, later joining their ranks and eventually becoming the team's leader.
Depends on the situation, the setting, whether there is prep, etc etc etc etc. Just check out the battle forums and search Captain America and you'll find a bunch of battles with him in it, read those and you'll get and idea.
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