Just to ask for alternate realities where good and evil are switch which would be in the same path. Braniac and Bunnie Rabbot alternate versions are two examples.

Brainiac from Earth 3 may be organic but he still brings doom to the universe. Instead of collecting every data and than destroying it, Assimilation is the preferred mthod for this version of Braniac.

Buns Rabbot is the alternate version of Bunnie Rabbot. Bunnie Rabbot fights for good when the freedom fighters rescued her. As this is alternate reality the Scourge abandon her when she was dieing from an illness. Kintobar, aka anti-robotnik, saved her and to repay her dept she fought alongside Kintobar.

I do not know how to categorize the Riddler family since they are very complicated. Any reality version seems to switch sides like Magneto’s family.